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The head chef, Cindy Wolf, looked at his résumé and noted that it consisted of irrelevant experience.However, Cindy did offer him a job to make cornbread and biscuits only, and this is what Goldman cites as the turning point in his career."I love motorcycles," Goldman, 39, told Us at the Hollywood premiere of . Even though I got in a wreck a little while ago and lost some toes — I had to promise my parents and everybody that I’d stop riding — but I can't." PHOTOS: Reality TV's breakout stars Reflecting back on the harrowing 2012 crash, Goldman said the accident itself hasn't deterred him in from pursuing his love for bikes. "It just made me make the choice — more consciously to say, ' I'm doing something that is very dangerous, but it’s something I love.'" PHOTOS: Stars who've been caught getting scared Goldman added that while his commute to and from work is risky, he feels at ease about his mode of transportation."I have to make peace with myself — that on my way to work, I’m really close to death," he confessed. Duff was born Jeffrey Adam Goldman — his older brother, Willie, is responsible for his nickname, Duffy.The brothers are still super close: Willie, a Los Angeles television executive, co-produces Duff's show. "I think serendipity did the job in the end, but the beginning of my culinary career simply involved working my a-- off in a variety of jobs," he says. "I walked a fine line between the law and the needs of my creatively fertile mind," he says. He decorated his first cake on his living room coffee table.

After working under acclaimed chefs in California, including a stagiaire position at the French Laundry In 2000, Goldman opened his own business called Charm City Cakes.Charm City Cakes frequently uses blow torches, as well as power tools such as grinders and drills to help create the underlying supports of cakes. "As hard as Willie tried to pronounce 'Jeffrey,' it kept coming out wrong," Duff says. Before he went on to study at the Culinary Institute of America and bake cakes for movie premieres and big-time events, Duff cooked at fast-food joints and greasy spoons in high school. In high school, Duff honed his artistic skills through graffiti — or "mural art," as he called it around his mom.“I can’t believe I’m one of those people,” Goldman said, “someone who flies in and then turns around the same day and flies out.” He’s like the James Brown of bakers — the hardest-working man in the cake business.He’s also in the middle of figuring out life after “Ace of Cakes.” After 10 seasons of the Food Network show that catapulted Goldman to chef-lebrity status but ended in February (to the chagrin of devoted fans), he moved to Los Angeles to open the West Coast version of his famed Baltimore cake shop and shot six episodes of his latest TV foray as host of the dessert program “Sugar High.” Shooting was two months of riding around on his Harley in Los Angeles, Chicago, Dallas, Philadelphia, Boston and New Orleans, eating desserts and talking to pastry chefs.He is the executive chef of the Baltimore-based Charm City Cakes shop which was featured in the Food Network reality television show Ace of Cakes, and his second Los Angeles-based shop Charm City Cakes West, which is featured in Food Network's Duff Till Dawn and "Cake Masters" series.